[(5-Cp)2Sn(-5-Cp)Na · PMDETA], a Compound with a Trigonal-Planar Paddle Wheel Triorganostannate Ion
1992 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
[(5-Cp)2Sn(-5-Cp)Na · PMDETA], a Compound with a Trigonal-Planar Paddle Wheel Triorganostannate Ion
Davidson, M. G.; Stalke, D. & Wright, D. S. (1992)
Angewandte Chemie / International Edition, 21(9) pp. 1226-1227. DOI: https://doi.org/10.1002/anie.199212261
Documents & Media
Details
- Authors
- Davidson, Matthew G.; Stalke, Dietmar; Wright, Dominic S.
- Abstract
- An organotin(II) anion with three 5-Cp ligands and a p. atom in a trigonal-planar environment are found in the title compound 1 (see diagram), obtained from the reaction of CpNa, [Cp2Sn], and PMDETA (mol ratio 1:1:1). This [Cp3Sn]- ion is linked to the Na+ ion by a -5-Cp bridge. Compound 1 is a polymeric array in the solid state due to intermolecular C(H) Na interactions. PMDETA = (Me2NCH2CH2)2NMe.
- Issue Date
- 1992
- Journal
- Angewandte Chemie / International Edition
- Language
- English
