Structure of bis(pentamethyldiethylenetriamine)disodium hexasulfide
1993 | journal article. A publication with affiliation to the University of Göttingen.
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Structure of bis(pentamethyldiethylenetriamine)disodium hexasulfide
Besser, S.; Herbst-Irmer, R.; Stalke, D.; Wright, D. S.; Snaith, R. & Brooker, A. T. (1993)
Acta Crystallographica / C, 49(8) pp. 1482-1483. DOI: https://doi.org/10.1107/S0108270193001167
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Details
- Authors
- Besser, Susanne; Herbst-Irmer, Regine; Stalke, Dietmar; Wright, Dominic S.; Snaith, Ronald; Brooker, Alan T.
- Abstract
- The new sodium sulfide compound, #-hexasulfidolt~2S1,S 6:2n 2S1,S 6_bis{[N_(dimethylaminoethyl)_N,N,,_ N'-trimethyl- 1,2-ethanediamine-t~3N, N',N"]sodium},[Na(pmdeta)]2[S6] (1) [pmdeta = (Me2NCH2CH2)2NMe],was obtained by reacting two equivalents of sodium hydride with elementary sulfur in toluene containing an excess of pmdeta at approximately 238 K. The crystal structure contains a central Na2p. ring in which both S atoms are part of an S~- residue. In addition, each Na atom is coordinated by a pmdeta molecule.
- Issue Date
- 1993
- Journal
- Acta Crystallographica / C
- Organization
- Fakultät für Chemie
- File Format
- application/pdf
- Language
- English
