Synthesis and Structure of the Disilagermirane R2Ge(SiR2)2 and the Solvent-Separated Ion Pair [Li([12]crown-4)2][GeR3]; (R = SiMe3)
1994 | journal article. A publication with affiliation to the University of Göttingen.
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Synthesis and Structure of the Disilagermirane R2Ge(SiR2)2 and the Solvent-Separated Ion Pair [Li([12]crown-4)2][GeR3]; (R = SiMe3)
Heine, A. & Stalke, D. (1994)
Angewandte Chemie / International Edition, 33(15/16) pp. 113-115. DOI: https://doi.org/10.1002/anie.199401131
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Details
- Authors
- Heine, Andreas; Stalke, Dietmar
- Abstract
- The disilagermirane 1 is obtained in good yields from (Me3Si)3 SiLi(thf) and GeCl2. The germyllithium compound 2 was also prepared; its anion, the higher homologue of the p. starting material for 1, might prove to be a versatile building block for a great variety of mixed three-membered rings containing the heavier elements of group 14.
- Issue Date
- 1994
- Journal
- Angewandte Chemie / International Edition
- Language
- English
