Molecular Solids as Ligands in Organometallic Chemistry: [CpTi6Na7F19·2.5thf] (Cp C5Me5) and [CpTi4Mg2F12·7thf], Links Between Ionic Solids and Organometallic Compounds
1994 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
Molecular Solids as Ligands in Organometallic Chemistry: [CpTi6Na7F19·2.5thf] (Cp C5Me5) and [CpTi4Mg2F12·7thf], Links Between Ionic Solids and Organometallic Compounds
Liu, F.-Q.; Kuhn, A.; Herbst-Irmer, R.; Stalke, D. & Roesky, H. W. (1994)
Angewandte Chemie / International Edition, 33(5) pp. 555-556. DOI: https://doi.org/10.1002/anie.199405551
Documents & Media
Details
- Authors
- Liu, Feng-Quan; Kuhn, Annja; Herbst-Irmer, Regine; Stalke, Dietmar; Roesky, Herbert W.
- Abstract
- Central NaF and MgF2 frameworks are present in the title compounds obtained from the reaction of [Cp TiF3] (Cp C5Me5) with elemental sodium and magnesium, respectively. In these reactions TiIV is reduced to TiIII. The Cp Ti units function as organometallics shields around the cagelike core and are responsible for the high solubility of the compounds.
- Issue Date
- 1994
- Journal
- Angewandte Chemie / International Edition
- Language
- English
