Synthesis and Structure of the First Organometallic Galloxane Hydroxide Mes6Ga6O4(OH)4
1994 | journal article. A publication with affiliation to the University of Göttingen.
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Synthesis and Structure of the First Organometallic Galloxane Hydroxide Mes6Ga6O4(OH)4
Storre, J.; Belgardt, T.; Stalke, D. & Roesky, H. W. (1994)
Angewandte Chemie / International Edition, 33(12) pp. 1244-1246. DOI: https://doi.org/10.1002/anie.199412441
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Details
- Authors
- Storre, Jens; Belgardt, Thomas; Stalke, Dietmar; Roesky, Herbert W.
- Abstract
- Controlled hydrolysis of (mesityl)2GaOH leads to the first structurally characterized galloxane hydroxide 1, which crystallizes as [l(thf)4]-6THF. The framework of 1 consists of a distorted Ga6 octahedron whose faces are capped alternately by 3-O or 3-OH ligands. Only the ipso-C and O atoms of the mesityl and four THF substituents, respectively, are shown in the picture on the right.
- Issue Date
- 1994
- Journal
- Angewandte Chemie / International Edition
- Language
- English
