Ruthenium( ii )-catalyzed C–H functionalizations on benzoic acids with aryl, alkenyl and alkynyl halides by weak-O-coordination

2016 | journal article. A publication with affiliation to the University of Göttingen.

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​Ruthenium( ii )-catalyzed C–H functionalizations on benzoic acids with aryl, alkenyl and alkynyl halides by weak-O-coordination​
Mei, R.; Zhu, C. & Ackermann, L.​ (2016) 
Chemical Communications52(89) pp. 13171​-13174​.​ DOI: https://doi.org/10.1039/C6CC07773K 

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Authors
Mei, Ruhuai; Zhu, Cuiju; Ackermann, Lutz
Abstract
C–H arylations of weakly coordinating benzoic acids were achieved by versatile ruthenium( ii ) catalysis with ample substrate scope.
C–H arylations of weakly coordinating benzoic acids were achieved by versatile ruthenium( ii ) catalysis with ample substrate scope. Thus, user-friendly ruthenium( ii ) biscarboxylate complexes modified with tricyclohexylphosphine enabled C–H functionalizations with aryl electrophiles. The unique versatility of the ruthenium( ii ) catalysis manifold was reflected by facilitating effective C–H activations with aryl, alkenyl and alkynyl halides.
Issue Date
2016
Journal
Chemical Communications 
ISSN
1359-7345
eISSN
1364-548X
ISSN
1359-7345
eISSN
1364-548X
Language
English

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