[Cu2R2BrLi(thf)3], R = Si(SiMe3)3–a complex containing five-coordinate silicon in a three-centre two-electron bond (thf = tetrahydrofuran)
1993 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
[Cu2R2BrLi(thf)3], R = Si(SiMe3)3–a complex containing five-coordinate silicon in a three-centre two-electron bond (thf = tetrahydrofuran)
Heine, A.; Herbst-Irmer, R. & Stalke, D. (1993)
Journal of the Chemical Society. Chemical communications,(23) pp. 1927-1731. DOI: https://doi.org/10.1039/C39930001729
Documents & Media
Details
- Authors
- Heine, Andreas; Herbst-Irmer, Regine ; Stalke, Dietmar
- Abstract
- The title compound is obtained from the reaction of (Me3Si)3SiLi(thf)3 with CuBr in n-hexane and structurally characterised by X-ray diffraction; in [Cu2R2BrLi(thf)3], R = Si(SiMe3)3 one silyl ligand is bridging a very short Cu–Cu bond, resulting in a three-centre two-electron bond, while the second is terminally bound to copper; the other copper atom is linked to a lithium atom via a Cu Br Li bridge.
- Issue Date
- 1993
- Journal
- Journal of the Chemical Society. Chemical communications
- Organization
- Fakultät für Chemie
- File Format
- application/pdf
- Language
- English
