Lanthanide alkoxides—III. Four-coordinate anionic neodymium(III) alkoxides and amides 1

1994 | journal article. A publication with affiliation to the University of Göttingen.

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​Lanthanide alkoxides—III. Four-coordinate anionic neodymium(III) alkoxides and amides 1​
Edelmann, F. T.; Steiner, A.; Stalke, D.; Gilje, J. W.; Jagner, S. & Håkanssons, M.​ (1994) 
Polyhedron13(4) pp. 539​-546​.​ DOI: https://doi.org/10.1016/S0277-5387(00)84729-4 

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Authors
Edelmann, Frank T.; Steiner, Alexander; Stalke, Dietmar; Gilje, John W.; Jagner, Susan; Håkanssons, Mikael
Abstract
Tetracoordinate anionic neodymium(III) alkoxides and amides are obtained by adduct formation of Nd[OC(tBu)3]3 (1) and Nd[N(SiMe3)2]3 (2) with either LiCl or LiOSiMe3. The compounds (THF)3Li(μ-Cl)Nd[OC(tBu)3]3 (3), (THF)3Li(μ-Cl)Nd [N(SiMe3)2]3 (4) and [Li(THF)4][(Me3Si)2N3Nd(OSiMe3)] (5) have been characterized by single-crystal X-ray analyses.
Issue Date
1994
Journal
Polyhedron 
Organization
Fakultät für Chemie 
File Format
application/pdf
Language
English

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